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Nuestra Señora de La Paz (Spanish: ; ;), is the administrative capital of Bolivia, as well as the departmental capital of La Paz Department, and the second largest city (in population) only after Santa Cruz de la Sierra (...) (from Wikipedia)

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From Trip: My South America Journey
By: GraemeBarrow

Day 57-59;
The drive around Lake Titicaca and through the altiplano to La Paz, Bolivia is impressive. Founded by Alonso de Mendoza in 1548, La Ciudad de Nuestra Señora de La Paz (the City of Our Lady of Peace) is a great place to explore on foot. Although Sucre is the official capital, La Paz is the Bolivian centre of commerce, finance and industry, and the de facto capital. This is a busy modern city, with its centre at the base
of a canyon 5 km (3 miles) wide, with sprawling impromptu housing all the way up the surrounding hillsides. The city is at nearly 4000 m (13,120 ft) above sea level, so visitors should be prepared for cool evenings and mornings.

Explore the city’s many fine museums or its historic ecclesiastical structures, such as the Iglesia de San Francisco, whose architectural details reflect the indigenous and
mestizo heritage of modern Bolivia. The city is also renowned for its many markets, including the Mercado de Hechicería (Witches’ Market), where Paceños and visitors may purchase potions and incantations made from all sorts of herbs, seeds, and secret ingredients to remedy any number of illnesses (real or imagined) and protect from evil spirits. There is also a thriving black market and a Carnaval market, where locals purchase carnival costumes. You’ll also find a wealth of shops selling all sorts of handicrafts, mainly alpaca wool products, silver jewellery, woven textiles and leather goods.

Optional activities in La Paz include museums, excursions to Tiahuanaco ruins (cradle of Inca civilization), a tour of the Valley of the Moon, or a visit to the world’s highest ski resort, Chacaltaya (5600 m/18,368 ft). To the south of the city is the Valley of the Moon, with crater-like formations made of sand.

Board an overnight bus in the evening of day 36 to Sucre.

La Paz to Sucre
Approximate distance: 416.40km
Estimate travel time: 14 hours